(Z)-N-[5-Bromo-2-(4-methylanilino)-3H-indol-3-ylidene]-4-methylaniline oxide
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منابع مشابه
(Z)-N-[5-Bromo-2-(4-methylanilino)-3H-indol-3-ylidene]-4-methylaniline oxide
The crystal structure of the title compound, C(22)H(18)BrN(3)O, is stabilized by π-π contacts [centroid-centroid distance = 3.476 (2) Å] between five-membered rings as well as inter-molecular C-H⋯O and C-H⋯N hydrogen bonds. An intra-molecular N-H⋯O hydrogen bond occurs. The benzene rings make a dihedral angle of 59.89 (8)°. The dihedral angles between the fused ring systemand the two benzene ri...
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The title compound, C(28)H(38)Br(2)N(2), is centrosymmetric with the mid-point of the central C-C bond of the butyl group located on an inversion center. The terminal benzene ring is approximately perpendicular to the central 1,4-diaza-butadiene mean plane [dihedral angle = 78.23 (3)°]. No hydrogen bonding or aromatic stacking is observed in the crystal structure.
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The asymmetric unit of the title compound, C(14)H(11)BrN(2)O(2), contains two independent mol-ecules connected into a dimer by inter-molecular N-H⋯O hydrogen bonds involving the amine and carbonyl groups. The dimers are further connected by O-H⋯O hydrogen bonds, forming chains running parallel to the a axis, which are stabilized through π-π stacking inter-actions, with a centroid-centroid dista...
متن کامل2-(4-Bromo-1H-indol-3-yl)acetonitrile
In the title compound, C(10)H(7)BrN(2), the non-H atoms, except the N atom of the acetonitrile group and the C atom bonded to it, lie in the least-squares plane defined by the atoms of the indole ring system (r.m.s deviation = 0.019 Å), with the N and C atom of the cyano group displaced by 2.278 (1) and 1.289 (1) Å, respectively, out of that plane. In the crystal, N-H⋯N hydrogen bonds link the ...
متن کاملN-(3-Bromo-5-methyl-2-pyridyl)-4-methylbenzenesulfonamide
In the mol-ecule of the title compound, C(13)H(13)BrN(2)O(2)S, the dihedral angle formed by the pyridine and benzene rings is 66.87 (3)°. An intra-molecular N-H⋯Br hydrogen bond is observed. In the crystal structure, N-H⋯O hydrogen bonds, C-H⋯π inter-actions and aromatic π-π stacking inter-actions [centroid-centroid distance = 3.757 (14) Å] link the mol-ecules into a three-dimensional network.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811000833